SHERWIN-WILLIAMS CO -- SWP EXTERIOR GLOSS OIL BASE PAINT, BASE C, A2G40 -- 8010-00N018232
===================== Product Identification ===================== Product ID:SWP EXTERIOR GLOSS OIL BASE PAINT, BASE C, A2G40 MSDS Date:04/23/1997 FSC:8010 NIIN:00N018232 MSDS Number: CFZGV === Responsible Party === Company Name:SHERWIN-WILLIAMS CO Address:101 PROSPECT AVE NW City:CLEVELAND State:OH ZIP:44115 Country:US Info Phone Num:216-566-2902 Emergency Phone Num:216-566-2917 CAGE:54636 === Contractor Identification === Company Name:SHERWIN-WILLIAMS CO THE Address:101 PROSPECT AVE NW Box:City:CLEVELAND State:OH ZIP:44115-1042 Country:US Phone:800-251-2486/216-566-2242 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:EFTS OF OVEREXP: ITS CARCINOGENICITY. PRLNG OVEREXP TO SOLV INGS MAY CAUSE ADVERSE EFTS TO LIVER, URINARY & (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: REPRO SYS. REPORTS HAVE ASSOCIATED REPEATED & PROLONGED OVEREXP TO SOLVS W/PERMANENT BRAIN & NERVOUS SYS DAMAGE. RTECS #:9999999ZZ Ingred Name:EXPLAN OF CARCIN: VOL 68, 1997: GROUP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994: ANTIC TO BE CARCIN. HUMAN: LUNG. RTECS #:9999999ZZ Ingred Name:OTHER PREC: INHALING CONTENTS CAN BE HARMFUL/FATAL. THIS COATING MAY CONTAIN MATLS CLASSIFIED AS NUISANCE (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: PARTICULATES WHICH MAY BE PRESENT AT HAZARDOUS LEVELS ONLY DURING SANDING/ABRADING OF THE DRIED FILM. RTECS #:9999999ZZ Ingred Name:CARBON BLACK; VP: 0.00 CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 0.2% OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3 Ingred Name:SOLVENT NAPHTHA, PETROLEUM, MEDIUM ALIPHATIC; (MINERAL SPIRITS) VP: 2.00 CAS:64742-88-7 RTECS #:WF3450000 Fraction by Wt: 9% OSHA PEL:100 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:SOLVENT NAPHTHA, PETROLEUM, MEDIUM ALIPHATIC; (MINERAL SPIRITS 140-FLASH) VP: 0.50 CAS:64742-88-7 RTECS #:WF3450000 Fraction by Wt: 24% OSHA PEL:100 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:XYLENE (SARA 313) (CERCLA) VP: 5.90 CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 2% OSHA PEL:100 PPM ACGIH TLV:100 PPM/150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:COBALT 2-ETHYLHEXANOATE; VP: 0.00 CAS:136-52-7 Fraction by Wt: 0.2% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (QUARTZ) CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 12% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERV SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON & POSS DEATH. SIGNS & SYMPS OF OVEREXP: HDCH, DIZZ, NAUS, LOSS OF COORD ARE INDICATIONS OF EXCESS E XPOS TO VAPS/SPRAY MISTS. REDNESS & ITCH/BURNING SENSATION MAY INDICATE EYE/EXCESS SKIN EXPOS. (EFTS OF OVEREXP) Explanation of Carcinogenicity:CARBON BLACK: IARC MONO, VOL 65, PG 149, 1996: GROUP 2B. ANIMAL: LUNG. SILICA, CRYSTALLINE-QUARTZ: IARC MONO, (ING 10) Effects of Overexposure:HLTH HAZ: CHRONIC: LONG TERM EXPOS TO HIGH LEVELS OF SILICA DUST, WHICH CAN OCCUR ONLY WHEN SANDING/ABRADING DRY FILM, MAY CAUSE LUNG DMG (SILICOSIS) & POSS CANCER. COBALT & COBALT CMPDS ARE CLASSIFIE D AS POSS CARCIN TO HUMANS (GROUP 2B) BASED ON EXPT ANIMAL DATA, HOWEVER, THERE IS INADEQ EVIDENCE IN HUMANS FOR (ING 8) Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHALATION: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. E YES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGESTION: GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:102F,39C Lower Limits:0.9% Upper Limits:7.0% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZ ARE PREF. WATER MAY BE USED TO COOL CLSD (SUP DAT) Unusual Fire/Explosion Hazard:KEEP CONTRS TIGHTLY CLSD. ISOLATE FROM HEAT, ELEC EQUIP, SPKS, & OPEN FLAME. CLSD CONTRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATION TO HOT (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST. AVOID CONT W/SKIN & EYES. CONTENTS COMBUST. KEEP AWAY FROM HEAT & OPEN FLAME. CONSULT NFPA CODE. Other Precautions:USE APPRVD BONDING & GROUNDING PROC. KEEP CONTR CLSD WHEN NOT IN USE. TRANSFER ONLY TO APPRVD CONTRS W/COMPLETE & APPROP LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. INTENTIONAL MI SUSE BY DELIBERATELY CONC & (ING 11) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERS EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMS BY VENT, WEAR PROPERLY FITTED ORG VAP/PARTICULATE RESP APPRVD BY NIOSH FOR PROT. WHEN SANDING/ABRADING DRIED FILM, WEAR DUST/MIST RESP APPRVD BY NI OSH FOR DUST WHICH MAY BE (SUP DAT) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS MAINT < APPLIC EXPOS LIMS. REFER TO OSHA STDS 1910.94, 1910.107, 1910.108. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH HANDS AFTER USING. Supplemental Safety and Health FIRE FIGHT PROC: CONTRS TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ: SURFS REQUIRES SPECIAL PREC. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HA Z. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. RESP PROT: GENERATED FROM THIS PROD, UNDERLYING PAINT/ABRASIVE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>281F,>138C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:1.02 VOC Pounds/Gallon:346 VOC Grams/Liter:3.03 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER Percent Volatiles by Volume:46 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM PROD MAY BE HAZ AS DEFINED UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE APPLIC EPA HAZ WASTE NUMBERS. INCIN IN APPRVD FACILITY. DO NOT INCIN CLSD CONTR. DISP OF I/A/W FED, STATE, & LOC REGS REGARDINGPOLLUTION. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.